| No. | Pos. | Nation | Player |
| 1 | GK | Germany GER | Marc-André ter Stegen |
| 2 | DF | Spain ESP | Héctor Bellerín |
| 3 | DF | Spain ESP | Gerard Piqué (vice-captain) |
| 4 | DF | Uruguay URU | Ronald Araújo |
| 5 | MF | Spain ESP | Sergio Busquets (captain) |
| 7 | FW | France FRA | Ousmane Dembélé |
| 8 | MF | Spain ESP | Pedri |
| 9 | FW | Poland POL | Robert Lewandowski |
| 10 | FW | Spain ESP | Ansu Fati |
| 11 | FW | Spain ESP | Ferran Torres |
| 14 | FW | Netherlands NED | Memphis Depay |
| 15 | DF | Denmark DEN | Andreas Christensen |
| 17 | DF | Spain ESP | Marcos Alonso |
| 18 | DF | Spain ESP | Jordi Alba (4th captain) |
| 19 | MF | Ivory Coast CIV | Franck Kessié |
| 20 | MF | Spain ESP | Sergi Roberto (3rd captain) |
| 21 | MF | Netherlands NED | Frenkie de Jong |
| 22 | FW | Brazil BRA | Raphinha |
| 23 | DF | France FRA | Jules Koundé |
| 24 | DF | Spain ESP | Eric García |
| 26 | GK | Spain ESP | Iñaki Peña |
| 30 | MF | Spain ESP | Gavi |
